If you need to run backup jobs that differ from the job that is assigned to the default user group, create a user-defined user group and assign the user accounts to it.
Procedure
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From the Command Center navigation pane, go to Protect > Microsoft 365.
The Microsoft 365 Overview page appears.
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On the Apps tab, click the OneDrive for Business app.
The app page appears.
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On the User groups tab, click Add user group.
The Add user group dialog box appears.
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In the User group name box, type a name for the user group.
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From the Backup plan list, select a backup plan.
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On the Users tab, click Add user.
The Add new content dialog box appears.
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In the Name column, select the user accounts that you want to add.
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Click Add, and then click Save.