The following services communicate with the SMTP server:
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CVd: Sends email notifications as part of the virtual machine expiration check.
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EvMgrS
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IIS/Web Server (W3wp)
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SendLogFiles: Sends log files in an email.
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ScheduleReport
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VMManagement: Sends email notifications when virtual machine creation succeeds or fails.
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Workflow: Sends emails when the workflow includes activities that include an email.