You can configure OneDrive for Business with Premium Microsoft 365 Backup Storage, which includes:
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Adding individual users
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Adding all users
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Adding AD groups
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Creating custom categories
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Adding OneDrive quota-enabled users
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Adding OneDrive license-enabled users
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Excluding an individual AD group
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Excluiding an individual user
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Excluding custom categories
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Deleting a user or a user group
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Excluding a user or a user group from backups of a OneDrive for Business app